True I don't think a Lucchese Boss as ever been the chief. Overall they're a stable Family, and Crea has helped with that, but I think that in today's day and age you're unlikely to see that position even being informally held like Massino did.
And even if such a rank were to exist again, I agree with m2w it would be a Genovese or Gambino Boss as they are the two strongest


"Don't ever go against the family again. Ever"- Michael Corleone