Here's the way I would answer the question...

The probability on Buffy being in Las Vegas is like you said 1 out of 40.

The odds on plaw being in Vegas is 1 out of 90.

The odds on both of you being in Vegas at the same time for any particular day is

1/40 * 1/90 = 1 / 3600, which seems really small.

However, you can correct it by knowing that people usually go to Vegas on weekends. Out of 52 weekends in a year, let's say 48 are Vegas eligible weekends (correcting for the holidays, etc.)

Therefore, Buffy is in Vegas 3 out of 48 weekends (= 1/16). Plaw is in Vegas 1 out of 48 weekends. The probability that Buffy and Plaw are together at the same time is:

1/16 * 1/48 = 1/768

Note that I'm doing the probabilities as separate independent events. It makes a difference if we know one of the parties is in Vegas to begin with.