I think almost all the ones he did were unsanctioned Captainbony.
Apart Bocchini that was a lucchese capo that was killed because punched DeMeo,all of the 100 murders was santioned (for example the murder of the abusing husband of Castellano daughter) or was people that are associate or people not involved in the life but there was a threat for Roy bussinesses.
Officially Castellano ordered the DeMeo murder because was on trial and DeMeo had attracted too much negative publicity.